{"id":11182,"date":"2024-09-10T09:55:53","date_gmt":"2024-09-10T07:55:53","guid":{"rendered":"https:\/\/lncmi.cnrs.fr\/?page_id=11182"},"modified":"2025-06-03T10:10:26","modified_gmt":"2025-06-03T08:10:26","slug":"chiralite-et-magnetisme","status":"publish","type":"page","link":"https:\/\/lncmi.cnrs.fr\/en\/optics-and-diluted-matter\/chiralite-et-magnetisme\/","title":{"rendered":"Chirality and magnetism"},"content":{"rendered":"<p>[et_pb_section fb_built=&#8221;1&#8243; fullwidth=&#8221;on&#8221; _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; background_enable_color=&#8221;off&#8221; background_image=&#8221;https:\/\/lncmi.cnrs.fr\/wp-content\/uploads\/2025\/02\/bandeau-MChD-2-scaled.jpg&#8221; background_size=&#8221;stretch&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_fullwidth_header title=&#8221;Chiralit\u00e9 et magn\u00e9tisme&#8221; text_orientation=&#8221;center&#8221; background_overlay_color=&#8221;rgba(0,0,0,0.2)&#8221; _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; background_color=&#8221;#FFFFFF&#8221; use_background_color_gradient=&#8221;on&#8221; background_color_gradient_type=&#8221;elliptical&#8221; background_color_gradient_stops=&#8221;#f4efe6 0%|#ffffff 100%&#8221; background_image=&#8221;https:\/\/lncmi.cnrs.fr\/wp-content\/uploads\/2025\/02\/bandeau-MChD-2-scaled.jpg&#8221; background_size=&#8221;contain&#8221; min_height=&#8221;262px&#8221; custom_padding=&#8221;||7px|||&#8221; text_shadow_style=&#8221;preset3&#8243; global_colors_info=&#8221;{}&#8221;][\/et_pb_fullwidth_header][\/et_pb_section][et_pb_section fb_built=&#8221;1&#8243; disabled_on=&#8221;on|on|off&#8221; _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; overflow-x=&#8221;auto&#8221; sticky_position=&#8221;top&#8221; overflow-x_tablet=&#8221;auto&#8221; overflow-x_phone=&#8221;&#8221; overflow-x_last_edited=&#8221;on|phone&#8221; locked=&#8221;off&#8221; global_colors_info=&#8221;{}&#8221; overflow-x__hover_enabled=&#8221;off|desktop&#8221;][et_pb_row column_structure=&#8221;1_6,1_6,1_6,1_6,1_6,1_6&#8243; 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_module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_button button_url=&#8221;#techniques&#8221; button_text=&#8221;Techniques&#8221; _builder_version=&#8221;4.26.0&#8243; _module_preset=&#8221;default&#8221; custom_button=&#8221;on&#8221; button_text_size=&#8221;15px&#8221; global_colors_info=&#8221;{}&#8221;][\/et_pb_button][\/et_pb_column][et_pb_column type=&#8221;1_6&#8243; _builder_version=&#8221;4.26.0&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_button button_url=&#8221;#publications&#8221; button_text=&#8221;Publications&#8221; _builder_version=&#8221;4.27.0&#8243; _module_preset=&#8221;default&#8221; custom_button=&#8221;on&#8221; button_text_size=&#8221;15px&#8221; global_colors_info=&#8221;{}&#8221;][\/et_pb_button][\/et_pb_column][\/et_pb_row][\/et_pb_section][et_pb_section fb_built=&#8221;1&#8243; module_id=&#8221;description&#8221; _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; min_height=&#8221;379px&#8221; custom_padding=&#8221;11px||2px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_row _builder_version=&#8221;4.25.2&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;0px||0px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;4_4&#8243; _builder_version=&#8221;4.25.2&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_text _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; width=&#8221;100%&#8221; min_height=&#8221;74px&#8221; custom_padding=&#8221;||0px|||&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<div class=\"prose prose-neutral max-w-none select-text overflow-x-auto text-wrap break-words dark:prose-invert prose-p:whitespace-break-spaces prose-code:m-0 prose-code:whitespace-break-spaces prose-pre:m-0 prose-pre:bg-[#1e1e1e] prose-pre:p-0 prose-ol:pl-8 font-light\">\n<p style=\"text-align: justify\"><strong>Chirality<\/strong> and <strong>magnetism<\/strong> have a common history which date back to the nineteen century. It is based on the similar optical response of chiral and magnetized media when exposed to circularly polarized light. This similarity has raised many attempts, often vains, on the possibility to control chiral systems with magnetic fields.<\/p>\n<\/div>\n<p>[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row column_structure=&#8221;1_2,1_2&#8243; _builder_version=&#8221;4.25.2&#8243; _module_preset=&#8221;default&#8221; min_height=&#8221;198px&#8221; custom_padding=&#8221;0px||3px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;1_2&#8243; _builder_version=&#8221;4.25.2&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_text _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; width=&#8221;100%&#8221; min_height=&#8221;230px&#8221; custom_margin=&#8221;||24px|||&#8221; custom_padding=&#8221;0px|0px||||&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<div class=\"prose prose-neutral max-w-none select-text overflow-x-auto text-wrap break-words dark:prose-invert prose-p:whitespace-break-spaces prose-code:m-0 prose-code:whitespace-break-spaces prose-pre:m-0 prose-pre:bg-[#1e1e1e] prose-pre:p-0 prose-ol:pl-8 font-light\">\n<p style=\"text-align: justify\"><span style=\"font-size: 14px\">On the basis of symmetry arguments, the interaction between chirality and magnetism is possible if the magnetic field is associated with another physical entity, such as electric current or light, even unpolarized. This association induces a &#8220;true chiral&#8221; influence, as defined by L. D. Barron. These two ways of associating light and electric current with magnetic fields are studied at the LNCMI since several years. They result in a different response of two enantiomers of a chiral system when unpolarized light (<strong>Magneto-Chiral Dichroism, MChD<\/strong>) or electric current (<strong>Magneto-Chiral Anisotopy, eMChA<\/strong>) are parallel\/antiparallel applied with respect to the applied magnetic field.<\/span><span style=\"font-size: 14px\"><\/span><\/p>\n<p style=\"text-align: justify\"><span style=\"font-size: 14px\">More recently, we are focusing also on the inverse effect, notably, the generation of enantiomeric excesses under a true chiral influence (<strong>Magneto-Chiral Photochemistry, <\/strong>\u00a0<strong>MChPh<\/strong>) or falsely chiral, or the generation of a magnetization by light irradiation in a magnetic field (<\/span><span style=\"font-size: 14px\"><strong>inverse Magneto-Chiral Dichroism<\/strong>,<strong>\u00a0iMChD<\/strong>).<\/span><\/p>\n<\/div>\n<p>[\/et_pb_text][\/et_pb_column][et_pb_column type=&#8221;1_2&#8243; _builder_version=&#8221;4.25.2&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_image src=&#8221;https:\/\/lncmi.cnrs.fr\/wp-content\/uploads\/2025\/03\/Figure-1.png&#8221; title_text=&#8221;Figure 1&#8243; align=&#8221;center&#8221; _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; width=&#8221;100%&#8221; module_alignment=&#8221;center&#8221; custom_margin=&#8221;-5px||||false|false&#8221; custom_margin_tablet=&#8221;70px||||false|false&#8221; custom_margin_phone=&#8221;70px||||false|false&#8221; custom_margin_last_edited=&#8221;on|desktop&#8221; custom_padding=&#8221;|||0px||&#8221; global_colors_info=&#8221;{}&#8221;][\/et_pb_image][\/et_pb_column][\/et_pb_row][\/et_pb_section][et_pb_section fb_built=&#8221;1&#8243; module_id=&#8221;personnel&#8221; _builder_version=&#8221;4.27.0&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;2px||0px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_row _builder_version=&#8221;4.25.2&#8243; _module_preset=&#8221;default&#8221; min_height=&#8221;439.1px&#8221; custom_padding=&#8221;||0px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;4_4&#8243; _builder_version=&#8221;4.25.2&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_text _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h3>Research staff<\/h3>\n<p>[\/et_pb_text][et_pb_code _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;]<div class='rt-container-fluid rt-team-container rt-pos-r rt-team-container-11189' id='rt-team-container-407058514'  data-layout='layout2' data-desktop-col='2'  data-tab-col='2'  data-mobile-col='1' data-sc-id='11189' data-popup-bg=''><div data-title='Loading ...' class='rt-row rt-content-loader layout2 ttp-even ttp-pre-loader'><div class=\"rt-col-md-6 rt-col-sm-6 rt-col-xs-12  even-grid-item rt-grid-item\" data-id=\"17728\"><div class=\"single-team-area\"><div class=\"img-area rt-col-sm-2 rt-col-xs-4 \"><figure><a class=\"\" data-id=\"17728\" target=\"_self\" href=\"https:\/\/lncmi.cnrs.fr\/en\/annuaire\/atzori-matteo\/\"><img loading=\"lazy\" decoding=\"async\" width=\"1536\" height=\"1536\" src=\"https:\/\/lncmi.cnrs.fr\/wp-content\/uploads\/2024\/09\/Matteo2-1-194x300-1-1-1-1536x1536.jpg\" class=\"img-responsive rt-team-img\" alt=\"ATZORI Matteo\" \/><\/a><\/figure><\/div><div class=\"rttm-content-area rt-col-sm-10 rt-col-xs-8 \"><h3><span class=\"team-name\"><a class=\"\" data-id=\"17728\" target=\"_self\" title=\"ATZORI Matteo\" href=\"https:\/\/lncmi.cnrs.fr\/en\/annuaire\/atzori-matteo\/\">ATZORI Matteo<\/a><\/span><\/h3><div class=\"tlp-position\"><a class=\"\" data-id=\"17728\" target=\"_self\" title=\"ATZORI Matteo\" href=\"https:\/\/lncmi.cnrs.fr\/en\/annuaire\/atzori-matteo\/\">Researcher<\/a><\/div><div class=\"contact-info\"><ul><li class=\"tlp-location\"><i class=\"fa fa-map-marker\"><\/i><span class=\"tlp-location\">Grenoble<\/span><\/li><\/ul><\/div><\/div><\/div><\/div><div class=\"rt-col-md-6 rt-col-sm-6 rt-col-xs-12  even-grid-item rt-grid-item\" data-id=\"17723\"><div class=\"single-team-area\"><div class=\"img-area rt-col-sm-2 rt-col-xs-4 \"><figure><a class=\"\" data-id=\"17723\" target=\"_self\" href=\"https:\/\/lncmi.cnrs.fr\/en\/annuaire\/rikken-geert\/\"><img loading=\"lazy\" decoding=\"async\" width=\"200\" height=\"300\" src=\"https:\/\/lncmi.cnrs.fr\/wp-content\/uploads\/2024\/09\/RIKKEN-200x300-1.jpg\" class=\"img-responsive rt-team-img\" alt=\"RIKKEN Geert\" \/><\/a><\/figure><\/div><div class=\"rttm-content-area rt-col-sm-10 rt-col-xs-8 \"><h3><span class=\"team-name\"><a class=\"\" data-id=\"17723\" target=\"_self\" title=\"RIKKEN Geert\" href=\"https:\/\/lncmi.cnrs.fr\/en\/annuaire\/rikken-geert\/\">RIKKEN Geert<\/a><\/span><\/h3><div class=\"tlp-position\"><a class=\"\" data-id=\"17723\" target=\"_self\" title=\"RIKKEN Geert\" href=\"https:\/\/lncmi.cnrs.fr\/en\/annuaire\/rikken-geert\/\">Researcher<\/a><\/div><div class=\"contact-info\"><ul><li class=\"tlp-location\"><i class=\"fa fa-map-marker\"><\/i><span class=\"tlp-location\">Toulouse<\/span><\/li><\/ul><\/div><\/div><\/div><\/div><div class=\"rt-col-md-6 rt-col-sm-6 rt-col-xs-12  even-grid-item rt-grid-item\" data-id=\"17855\"><div class=\"single-team-area\"><div class=\"img-area rt-col-sm-2 rt-col-xs-4 \"><figure><a class=\"\" data-id=\"17855\" target=\"_self\" href=\"https:\/\/lncmi.cnrs.fr\/en\/annuaire\/train-cyrille\/\"><img loading=\"lazy\" decoding=\"async\" width=\"632\" height=\"664\" src=\"https:\/\/lncmi.cnrs.fr\/wp-content\/uploads\/2024\/09\/TRAIN-Cyrille-1024x683-1.jpg\" class=\"img-responsive rt-team-img\" alt=\"TRAIN Cyrille\" \/><\/a><\/figure><\/div><div class=\"rttm-content-area rt-col-sm-10 rt-col-xs-8 \"><h3><span class=\"team-name\"><a class=\"\" data-id=\"17855\" target=\"_self\" title=\"TRAIN Cyrille\" href=\"https:\/\/lncmi.cnrs.fr\/en\/annuaire\/train-cyrille\/\">TRAIN Cyrille<\/a><\/span><\/h3><div class=\"tlp-position\"><a class=\"\" data-id=\"17855\" target=\"_self\" title=\"TRAIN Cyrille\" href=\"https:\/\/lncmi.cnrs.fr\/en\/annuaire\/train-cyrille\/\">Professor<\/a><\/div><div class=\"contact-info\"><ul><li class=\"tlp-location\"><i class=\"fa fa-map-marker\"><\/i><span class=\"tlp-location\">Grenoble<\/span><\/li><\/ul><\/div><\/div><\/div><\/div><div class=\"rt-loading-overlay\"><\/div><div class=\"rt-loading rt-ball-clip-rotate\"><div><\/div><\/div><\/div><\/div>[\/et_pb_code][et_pb_text _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h3>Temporary research staff<\/h3>\n<p>[\/et_pb_text][et_pb_code _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;]<div class='rt-container-fluid rt-team-container rt-pos-r rt-team-container-19138' id='rt-team-container-785577987'  data-layout='layout2' data-desktop-col='2'  data-tab-col='2'  data-mobile-col='1' data-sc-id='19138' data-popup-bg=''><div data-title='Loading ...' class='rt-row rt-content-loader layout2 ttp-even ttp-pre-loader'><div class=\"rt-col-md-6 rt-col-sm-6 rt-col-xs-12  even-grid-item rt-grid-item\" data-id=\"17760\"><div class=\"single-team-area\"><div class=\"img-area rt-col-sm-2 rt-col-xs-4 \"><figure><a class=\"\" data-id=\"17760\" target=\"_self\" href=\"https:\/\/lncmi.cnrs.fr\/en\/annuaire\/atirojwanich-inkarat\/\"><img loading=\"lazy\" decoding=\"async\" width=\"1536\" height=\"1536\" src=\"https:\/\/lncmi.cnrs.fr\/wp-content\/uploads\/2024\/09\/picto-portrait-1536x1536.jpg\" class=\"img-responsive rt-team-img\" alt=\"ATIROJWANICH Inkarat\" \/><\/a><\/figure><\/div><div class=\"rttm-content-area rt-col-sm-10 rt-col-xs-8 \"><h3><span class=\"team-name\"><a class=\"\" data-id=\"17760\" target=\"_self\" title=\"ATIROJWANICH Inkarat\" href=\"https:\/\/lncmi.cnrs.fr\/en\/annuaire\/atirojwanich-inkarat\/\">ATIROJWANICH Inkarat<\/a><\/span><\/h3><div class=\"contact-info\"><ul><li class=\"tlp-location\"><i class=\"fa fa-map-marker\"><\/i><span class=\"tlp-location\">Grenoble<\/span><\/li><\/ul><\/div><\/div><\/div><\/div><div class=\"rt-loading-overlay\"><\/div><div class=\"rt-loading rt-ball-clip-rotate\"><div><\/div><\/div><\/div><\/div>[\/et_pb_code][et_pb_code _builder_version=&#8221;4.27.4&#8243; 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background_color=&#8221;#F5701E&#8221; custom_button=&#8221;on&#8221; button_border_radius=&#8221;100px&#8221; button_font=&#8221;Verdana||||||||&#8221; button_alignment=&#8221;left&#8221; width=&#8221;70%&#8221; module_alignment=&#8221;center&#8221; content_width=&#8221;100%&#8221; height=&#8221;528px&#8221; height_tablet=&#8221;300px&#8221; height_phone=&#8221;350px&#8221; height_last_edited=&#8221;on|phone&#8221; max_height=&#8221;300px&#8221; max_height_tablet=&#8221;300px&#8221; max_height_phone=&#8221;350px&#8221; max_height_last_edited=&#8221;on|desktop&#8221; custom_margin=&#8221;25px|25px|25px|25px|true|true&#8221; custom_padding=&#8221;60px||324px|329px|false|false&#8221; auto=&#8221;on&#8221; auto_speed=&#8221;10000&#8243; hover_transition_duration=&#8221;500ms&#8221; hover_transition_speed_curve=&#8221;ease-in&#8221; body_font_size_tablet=&#8221;&#8221; body_font_size_phone=&#8221;15px&#8221; body_font_size_last_edited=&#8221;on|phone&#8221; button_text_size_tablet=&#8221;17px&#8221; 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box_shadow_spread__hover=&#8221;-10px&#8221; box_shadow_spread__hover_enabled=&#8221;on|hover&#8221;][\/et_pb_fullwidth_post_slider][\/et_pb_section][et_pb_section fb_built=&#8221;1&#8243; admin_label=&#8221;Th\u00e8mes de recherche&#8221; module_id=&#8221;themes&#8221; _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; background_enable_color=&#8221;off&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_row _builder_version=&#8221;4.25.2&#8243; _module_preset=&#8221;default&#8221; min_height=&#8221;78.2px&#8221; custom_padding=&#8221;34px||26px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;4_4&#8243; _builder_version=&#8221;4.25.2&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_text _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h3>Topics<\/h3>\n<p>[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row _builder_version=&#8221;4.27.0&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;3px||3px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;4_4&#8243; _builder_version=&#8221;4.27.0&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_text _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;||0px|||&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<p style=\"text-align: justify\"><strong>Magn<\/strong><strong>eto-Chiral <\/strong><strong>Dichroism (MChD):<\/strong><\/p>\n<p style=\"text-align: justify\"><strong><\/strong><\/p>\n<div>\n<p><span>Magneto-Chiral Dichroism (MChD) represents the differential absoprtion (or emission) that chiral materials show when light is transmitted (or emitted) along a magnetic field applied parallel or antiparallel with respect to the light wavevector.<\/span><\/p>\n<p><span><\/span><\/p>\n<\/div>\n<div>\n<p><span lang=\"EN-GB\">The first experimental demonstration of this effect was done at the LNCMI on enantiopure emissive Eu(III) complexes. Since then, we experimentally investigate the parameters that drives MChD in chiral molecular and nanostructured systems based on transition metals or lanthanide ions. Theoretical support is provided by external collaborators.<\/span><\/p>\n<p><span lang=\"EN-GB\"><\/span><\/p>\n<\/div>\n<div><span lang=\"EN-GB\">Recently, we have design and prepared a Dysprosium(III) chiral complex with remanent magnetization at low temperature. MChD measurements on this compound have allowed us to reproduce the hysteresis cycle through light absorption measurements under magnetic field. This study has thus demonstrated that is possible to probe the magnetic state of magnetic chiral systems with the need of circular light polarization.<\/span><\/div>\n<div><\/div>\n<p>[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row column_structure=&#8221;1_2,1_2&#8243; _builder_version=&#8221;4.25.2&#8243; _module_preset=&#8221;default&#8221; module_alignment=&#8221;center&#8221; custom_margin=&#8221;22px|auto||auto||&#8221; custom_padding=&#8221;0px||28px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;1_2&#8243; _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_image src=&#8221;https:\/\/lncmi.cnrs.fr\/wp-content\/uploads\/2025\/06\/Figure_SMM-1024&#215;582.jpeg&#8221; title_text=&#8221;Figure_SMM&#8221; align=&#8221;center&#8221; _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; max_width=&#8221;63%&#8221; global_colors_info=&#8221;{}&#8221;][\/et_pb_image][\/et_pb_column][et_pb_column type=&#8221;1_2&#8243; _builder_version=&#8221;4.25.2&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_text _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<p><strong><span lang=\"EN-GB\">A new method to probe magnetic memories<\/span><\/strong><\/p>\n<p>M. S. Raju, K. Paillot,\u00a0 I. Breslavetz, G. Novitchi, G. L. J. A. Rikken, C. Train, M. Atzori<br \/><a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.4c08684\">J. Am. Chem. Soc. 2024, 146, 23616<\/a><\/p>\n<p><a href=\"https:\/\/www.inc.cnrs.fr\/fr\/cnrsinfo\/une-nouvelle-maniere-de-lire-les-memoires-magnetiques\">Press communication CNRS Chimie<\/a><\/p>\n<p>&nbsp;<\/p>\n<p>[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row column_structure=&#8221;3_5,2_5&#8243; _builder_version=&#8221;4.27.0&#8243; _module_preset=&#8221;default&#8221; min_height=&#8221;390.4px&#8221; custom_padding=&#8221;2px||0px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;3_5&#8243; _builder_version=&#8221;4.27.0&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_text _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; min_height=&#8221;297px&#8221; custom_margin=&#8221;-59px||-51px|||&#8221; hover_enabled=&#8221;0&#8243; global_colors_info=&#8221;{}&#8221; sticky_enabled=&#8221;0&#8243;]<\/p>\n<div>\n<p><strong><span lang=\"EN-GB\">Magn<\/span><\/strong><strong><span lang=\"EN-GB\">e<\/span><\/strong><strong><span lang=\"EN-GB\">to-Chiral<\/span><\/strong><strong><span lang=\"EN-GB\"> Photochemistry<\/span><\/strong><strong><span lang=\"EN-GB\"> (MChPh):<\/span><\/strong><span lang=\"EN-GB\"><\/span><\/p>\n<p><strong><span lang=\"EN-GB\"><\/span><\/strong><\/p>\n<\/div>\n<div>\n<p><span lang=\"EN-GB\">Given that the \u201cdirect\u201d effect of unpolarized light and magnetic fields on chiral systems, such as MChD, have been clearly demonstrated, the inverse effects, such as the generation of an enantiomeric excess (ee) when a racemic mixture or a prochiral system are exposed to an external chiral influence, are also possible.<\/span><\/p>\n<\/div>\n<div>\n<p><span lang=\"EN-GB\"><br \/>On the basis of the results achieved through the investigation of MChD in the visible range, we are now investigating Magneto-Chiral Photochemistry (MChPh), that is, photochemistry of chiral systems under magnetic field. The irradiation of a racemic mixture with a unpolarized laser beam in magnetic fields has provided an ee of the tris(oxalato)chromate(III) complex and this mechanism proposed as one of the possible origins of moleculear homochirality of life on Earth.<\/span><\/p>\n<\/div>\n<div>\n<p><span lang=\"EN-GB\"><br \/>These studies have been recently reinitiated with measurements under much higher magnetic fields and it will be extended to biological relevant molecular systems in the frame of the project <a href=\"https:\/\/anr.fr\/Project-ANR-23-CE07-0015\">ANR JCJC PRINCIPE<\/a>.<\/span><\/p>\n<p><span lang=\"EN-GB\"><\/span><\/p>\n<\/div>\n<p>[\/et_pb_text][\/et_pb_column][et_pb_column type=&#8221;2_5&#8243; _builder_version=&#8221;4.27.0&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_image src=&#8221;https:\/\/lncmi.cnrs.fr\/wp-content\/uploads\/2025\/03\/Schermata-2022-10-14-alle-14.29.09.png&#8221; title_text=&#8221;Schermata 2022-10-14 alle 14.29.09&#8243; _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; custom_margin=&#8221;-3px||-3px||true|false&#8221; global_colors_info=&#8221;{}&#8221;][\/et_pb_image][\/et_pb_column][\/et_pb_row][et_pb_row column_structure=&#8221;3_5,2_5&#8243; _builder_version=&#8221;4.27.0&#8243; _module_preset=&#8221;default&#8221; min_height=&#8221;197.2px&#8221; custom_padding=&#8221;13px|||||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;3_5&#8243; _builder_version=&#8221;4.27.0&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_text _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<p><strong>Response to a falsely chiral influence :<\/strong><\/p>\n<p>Effects comparable to magneto-chiral effects have been predicted when a certain system is subjected to an influence defined by L. D. Barron as \u201cfalsely chiral\u201d. Thus, the Curie-de Gennes conjecture predicts that the application of a collinear magnetic and electric field is likely to produce an enantiomeric excess from an initially racemic mixture. We try to demonstrate this conjecture experimentally. We have obtained encouraging preliminary results, but these need to be reproduced and extended in order to establish the relevance of this more than century-old conjecture.<\/p>\n<p>&nbsp;<\/p>\n<p>[\/et_pb_text][\/et_pb_column][et_pb_column type=&#8221;2_5&#8243; _builder_version=&#8221;4.27.0&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_image src=&#8221;https:\/\/lncmi.cnrs.fr\/wp-content\/uploads\/2025\/02\/Curie-deGennes.jpg&#8221; _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; custom_margin=&#8221;34px||||false|false&#8221; global_colors_info=&#8221;{}&#8221;][\/et_pb_image][\/et_pb_column][\/et_pb_row][\/et_pb_section][et_pb_section fb_built=&#8221;1&#8243; module_id=&#8221;techniques&#8221; _builder_version=&#8221;4.27.0&#8243; _module_preset=&#8221;default&#8221; min_height=&#8221;371.2px&#8221; custom_margin=&#8221;-4px|||||&#8221; custom_padding=&#8221;6px||7px|||&#8221; locked=&#8221;off&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_row _builder_version=&#8221;4.26.0&#8243; _module_preset=&#8221;default&#8221; min_height=&#8221;98.4px&#8221; custom_padding=&#8221;0px||0px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;4_4&#8243; _builder_version=&#8221;4.26.0&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_text module_id=&#8221;techniques&#8221; _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h2 class=\"entry-title\">Experimental Techniques<\/h2>\n<div><\/div>\n<p>[\/et_pb_text][et_pb_toggle title=&#8221;Magneto-Chiral Dichroism (MChD) measurements&#8221; _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; width=&#8221;100%&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<p>To measure the Magneto-Chiral Dichroism associated with the electronic transitions in the UV-Vis-NIR, an experimental setup based on a signal detection synchronized with magnetic field change has been developed at LNCMI. The measurment probe is mobile. It can be placed in a superconducting magnet or in resistive magnets, enabling measurements up to 9 T. Measurements can be taken over a very wide range of wavelengths, from 2.2 K to 290 K.<\/p>\n<p>[\/et_pb_toggle][et_pb_toggle title=&#8221;Natural Circular Dichroism (NCD) and Magnetic Circular Dichroism (MCD) measurements&#8221; _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; locked=&#8221;off&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<p>Pour \u00e9tudier les propri\u00e9t\u00e9s chiroptiques des syst\u00e8mes chiraux et magn\u00e9tiques, nous disposons de deux spectrophotophotom\u00e8tres (JASCO J1500, Olis DSM17). Un cryostat optique permet d&#8217;\u00e9tudier le Dichro\u00efsme Circulaire Naturel (NCD) sur une large gamme de longueurs d&#8217;onde jusqu&#8217;\u00e0 5K. Nous d\u00e9veloppons actuellement l&#8217;impl\u00e9mentation du champ magn\u00e9tique afin de pouvoir mesurer le Dichro\u00efsme Circulaire Magn\u00e9tique (MCD) dans les m\u00eames conditions.<\/p>\n<p>We have two spectrophotometer to study the chiroptical properties of chiral and magnetic systems (JASCO J1500, Olis DSM17). An optical cryostat enables us to study Natural Circular Dichroism (NCD) over a wide range of wavelengths down to 5 K. We are currently developing a Magnetic Circular Dichroism (MCD) setuot under the same conditions and magnetic fields up to 6 T.<\/p>\n<p>[\/et_pb_toggle][\/et_pb_column][\/et_pb_row][\/et_pb_section][et_pb_section fb_built=&#8221;1&#8243; admin_label=&#8221;Publications&#8221; module_id=&#8221;publications&#8221; _builder_version=&#8221;4.27.0&#8243; _module_preset=&#8221;default&#8221; min_height=&#8221;808.2px&#8221; custom_margin=&#8221;-4px|||||&#8221; custom_padding=&#8221;2px||5px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_row _builder_version=&#8221;4.25.2&#8243; _module_preset=&#8221;default&#8221; min_height=&#8221;86.4px&#8221; custom_margin=&#8221;1px|auto||auto||&#8221; custom_padding=&#8221;3px||22px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;4_4&#8243; _builder_version=&#8221;4.25.2&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_text _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h3>Publications<\/h3>\n<p>[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row _builder_version=&#8221;4.25.2&#8243; _module_preset=&#8221;default&#8221; min_height=&#8221;86.4px&#8221; custom_padding=&#8221;3px||0px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;4_4&#8243; _builder_version=&#8221;4.25.2&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_text _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; min_height=&#8221;481.5px&#8221; custom_padding=&#8221;6px|||||&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h4><strong><em>Selected Publications<\/em><\/strong><\/h4>\n<p><strong><\/strong><\/p>\n<p><strong>Optical Readout of Single-Molecule Magnetic Memories with Unpolarized Light<\/strong><br \/>M. S. Raju, K. Paillot, I. Breslavetz, G. Novitchi, G. L. J. A. Rikken, C. Train*, M. Atzori*<br \/><a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.4c08684\">J. Am. Chem. Soc. 2024, 146, 23616<\/a><\/p>\n<p><strong>Multifunctional Helicene-Based Ytterbium Coordination Polymer Displaying Circularly Polarized Luminescence, Slow Magnetic Relaxation and Room Temperature Magneto-Chiral Dichroism<\/strong><br \/>K. Dhbaibi, H. Douib, M. Grasser, V. Dorcet, L. Favereau, O. Cador, B. Le Guennic, F. Riob\u00e9, O. Maury, S. Guy, A. Bensalah\u2010Ledoux, B. Baguenard, C. Train, G. Rikken, M. Atzori,* F. Pointillart,* J. Crassous*<br \/><a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202215558\">Angew. Chem. Int. Ed. 2022, e202215558<\/a><\/p>\n<p><strong>Magnetic 3d-4f Chiral Clusters Showing Metal-site Selective Magneto-Chiral Dichroism<\/strong><br \/>X. Wang, S.-Q. Wang, J.-N. Chen, J.-H. Jia, C. Wang, K. Paillot, I. Breslavetz, L.-S. Long, L.-S. Zheng, G. L. J. A. Rikken, C. Train, X.-J. Kong* and M. Atzori*<br \/><a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.2c03049\">J. Am. Chem. Soc. 2022, 144, 8837<\/a><\/p>\n<p><strong>Validation of Microscopic Magneto-Chiral Dichroism Theory<\/strong><br \/>M. Atzori, H. Ludowieg, \u00c1. Valent\u00edn-P\u00e9rez, M. Cortijo, I. Breslavetz, K. Paillot, P. Rosa, C. Train, J. Autschbach, E. A. Hillard, G. L. J. A. Rikken*<br \/><a href=\"https:\/\/www.science.org\/doi\/10.1126\/sciadv.abg2859\">Sci. Adv. 2021, 7, eabg2859<\/a><\/p>\n<p><strong>A Chiral Prussian Blue Analogue Pushes Magneto-Chiral Dichroism Limits<\/strong><br \/>M. Atzori*, I. Breslavetz, K. Paillot, K. Inoue, G. L. J. A. Rikken, C. Train*<br \/><a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.9b10970\">J. Am. Chem. Soc. 2019, 141, 20022<\/a><\/p>\n<p>[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row _builder_version=&#8221;4.27.2&#8243; _module_preset=&#8221;default&#8221; locked=&#8221;off&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;4_4&#8243; _builder_version=&#8221;4.27.2&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_toggle title=&#8221;All publications (HAL server)&#8221; _builder_version=&#8221;4.27.4&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<p><span><div class=\"wp-rss-template-container\" data-wpra-template=\"default\" data-template-ctx=\"eyJzb3VyY2VzIjoiMTMyNzEifQ==\">\n    <div class=\"wp-rss-aggregator wpra-list-template  \" data-page=\"1\">\n    \n    \n<ul class=\"wpra-item-list rss-aggregator wpra-item-list--bullets wpra-item-list--default\"\n    start=\"1\">\n                        <li class=\"wpra-item feed-item \">\n            \n            \n\n    <a  href=\"https:\/\/hal.science\/hal-05526002v1\" target=\"_blank\" rel=\"nofollow\" class=\"\">[hal-05526002] Observation of acoustic magneto-chiral anisotropy in \u03b1-quartz<\/a>\n\n\n\n\n\n\n<div class=\"wprss-feed-meta\">\n    \n            <span class=\"feed-date\">\n            Published on Hal on 2026-02-24\n        <\/span>\n    \n    <\/div>\n\n\n\n\n\n            \n        <\/li>\n                    <li class=\"wpra-item feed-item \">\n            \n            \n\n    <a  href=\"https:\/\/univ-angers.hal.science\/hal-05395520v1\" target=\"_blank\" rel=\"nofollow\" class=\"\">[hal-05395520] Chiral Metallic DM-EDT-TTF Radical Cation Salts: Anion Size Dependent Structural and Electronic Transitions, Charge Ordering and Chirality Induced Spin Selectivity<\/a>\n\n\n\n\n\n\n<div class=\"wprss-feed-meta\">\n    \n            <span class=\"feed-date\">\n            Published on Hal on 2025-12-03\n        <\/span>\n    \n    <\/div>\n\n\n\n\n\n            \n        <\/li>\n                    <li class=\"wpra-item feed-item \">\n            \n            \n\n    <a  href=\"https:\/\/hal.science\/hal-05168989v1\" target=\"_blank\" rel=\"nofollow\" class=\"\">[hal-05168989] Modulated Ligand\u2013Ligand Exchange Coupling and Elusive Spinmerism in a Bis(verdazyl)iron(II) Complex<\/a>\n\n\n\n\n\n\n<div class=\"wprss-feed-meta\">\n    \n            <span class=\"feed-date\">\n            Published on Hal on 2025-07-18\n        <\/span>\n    \n    <\/div>\n\n\n\n\n\n            \n        <\/li>\n                    <li class=\"wpra-item feed-item \">\n            \n            \n\n    <a  href=\"https:\/\/hal.science\/hal-04886984v1\" target=\"_blank\" rel=\"nofollow\" class=\"\">[hal-04886984] Chirality meets magnetism: strategies to induce chirality to magnetic nanoparticles<\/a>\n\n\n\n\n\n\n<div class=\"wprss-feed-meta\">\n    \n            <span class=\"feed-date\">\n            Published on Hal on 2025-01-14\n        <\/span>\n    \n    <\/div>\n\n\n\n\n\n            \n        <\/li>\n                    <li class=\"wpra-item feed-item \">\n            \n            \n\n    <a  href=\"https:\/\/hal.science\/hal-04830857v1\" target=\"_blank\" rel=\"nofollow\" class=\"\">[hal-04830857] Macroscopic magneto-chiroptical metasurfaces<\/a>\n\n\n\n\n\n\n<div class=\"wprss-feed-meta\">\n    \n            <span class=\"feed-date\">\n            Published on Hal on 2024-12-11\n        <\/span>\n    \n    <\/div>\n\n\n\n\n\n            \n        <\/li>\n                    <li class=\"wpra-item feed-item \">\n            \n            \n\n    <a  href=\"https:\/\/hal.science\/hal-04830851v1\" target=\"_blank\" rel=\"nofollow\" class=\"\">[hal-04830851] Radiofrequency to Microwave Coherent Manipulation of an Organometallic Electronic Spin Qubit Coupled to a Nuclear Qudit<\/a>\n\n\n\n\n\n\n<div class=\"wprss-feed-meta\">\n    \n            <span class=\"feed-date\">\n            Published on Hal on 2024-12-11\n        <\/span>\n    \n    <\/div>\n\n\n\n\n\n            \n        <\/li>\n                    <li class=\"wpra-item feed-item \">\n            \n            \n\n    <a  href=\"https:\/\/hal.science\/hal-04830848v1\" target=\"_blank\" rel=\"nofollow\" class=\"\">[hal-04830848] Temperature Dependence of Spin\u2013Phonon Coupling in [VO(acac) 2 ]: A Computational and Spectroscopic Study<\/a>\n\n\n\n\n\n\n<div class=\"wprss-feed-meta\">\n    \n            <span class=\"feed-date\">\n            Published on Hal on 2024-12-11\n        <\/span>\n    \n    <\/div>\n\n\n\n\n\n            \n        <\/li>\n                    <li class=\"wpra-item feed-item \">\n            \n            \n\n    <a  href=\"https:\/\/hal.science\/hal-04751511v1\" target=\"_blank\" rel=\"nofollow\" class=\"\">[hal-04751511] Magnetochiral Dichroism in Nuclear Magnetic Resonance: Traveling Wave Enantioselective NMR<\/a>\n\n\n\n\n\n\n<div class=\"wprss-feed-meta\">\n    \n            <span class=\"feed-date\">\n            Published on Hal on 2024-10-29\n        <\/span>\n    \n    <\/div>\n\n\n\n\n\n            \n        <\/li>\n                    <li class=\"wpra-item feed-item \">\n            \n            \n\n    <a  href=\"https:\/\/hal.science\/hal-04751588v1\" target=\"_blank\" rel=\"nofollow\" class=\"\">[hal-04751588] Traveling Wave Enantioselective Electron Paramagnetic Resonance<\/a>\n\n\n\n\n\n\n<div class=\"wprss-feed-meta\">\n    \n            <span class=\"feed-date\">\n            Published on Hal on 2024-10-24\n        <\/span>\n    \n    <\/div>\n\n\n\n\n\n            \n        <\/li>\n                    <li class=\"wpra-item feed-item \">\n            \n            \n\n    <a  href=\"https:\/\/hal.science\/hal-04268142v1\" target=\"_blank\" rel=\"nofollow\" class=\"\">[hal-04268142] Comparing Electrical Magnetochiral Anisotropy and Chirality-Induced Spin Selectivity<\/a>\n\n\n\n\n\n\n<div class=\"wprss-feed-meta\">\n    \n            <span class=\"feed-date\">\n            Published on Hal on 2024-01-05\n        <\/span>\n    \n    <\/div>\n\n\n\n\n\n            \n        <\/li>\n                    <li class=\"wpra-item feed-item \">\n            \n            \n\n    <a  href=\"https:\/\/hal.science\/hal-04183996v1\" target=\"_blank\" rel=\"nofollow\" class=\"\">[hal-04183996] Dielectric magnetochiral anisotropy in triglycine sulfate<\/a>\n\n\n\n\n\n\n<div class=\"wprss-feed-meta\">\n    \n            <span class=\"feed-date\">\n            Published on Hal on 2023-11-07\n        <\/span>\n    \n    <\/div>\n\n\n\n\n\n            \n        <\/li>\n                    <li class=\"wpra-item feed-item \">\n            \n            \n\n    <a  href=\"https:\/\/hal.science\/hal-04005952v1\" target=\"_blank\" rel=\"nofollow\" class=\"\">[hal-04005952] Coherent manipulation of molecular qudits by broadband NMR<\/a>\n\n\n\n\n\n\n<div class=\"wprss-feed-meta\">\n    \n            <span class=\"feed-date\">\n            Published on Hal on 2023-02-27\n        <\/span>\n    \n    <\/div>\n\n\n\n\n\n            \n        <\/li>\n                    <li class=\"wpra-item feed-item \">\n            \n            \n\n    <a  href=\"https:\/\/hal.science\/hal-03807943v1\" target=\"_blank\" rel=\"nofollow\" class=\"\">[hal-03807943] Detection of the Faraday Chiral Anisotropy<\/a>\n\n\n\n\n\n\n<div class=\"wprss-feed-meta\">\n    \n            <span class=\"feed-date\">\n            Published on Hal on 2022-10-10\n        <\/span>\n    \n    <\/div>\n\n\n\n\n\n            \n        <\/li>\n                    <li class=\"wpra-item feed-item \">\n            \n            \n\n    <a  href=\"https:\/\/hal.science\/hal-03807926v1\" target=\"_blank\" rel=\"nofollow\" class=\"\">[hal-03807926] Dielectric magnetochiral anisotropy<\/a>\n\n\n\n\n\n\n<div class=\"wprss-feed-meta\">\n    \n            <span class=\"feed-date\">\n            Published on Hal on 2022-10-10\n        <\/span>\n    \n    <\/div>\n\n\n\n\n\n            \n        <\/li>\n        <\/ul>\n\n        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